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Herbicide mixtures

A herbicidal composition comprises a carrier, a first herbicide and a second herbicide which is 3-(1-amino)ethylidene-5-methyl-furan-2,4-dione.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Extended knowledge of (S)-4-Hydroxydihydrofuran-2(3H)-one

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Hydrolysis of chitosan to yield levulinic acid and 5-hydroxymethylfurfural in water under microwave irradiation

A novel route has been developed that yields levulinic acid (4-oxopentanoic acid, LA) and 5-hydroxymethylfurfural (5-HMF) from chitosan. Hydrolysis of chitosan was performed in the presence of a range of Lewis acids with SnCl 4¡¤5H2O providing the best results. All reactions were performed in sealed vessels under microwave irradiation at 200 C for 30 min. Typical pressures achieved were 17 to 19 bar. 23.9 wt% LA was produced from 100 mg chitosan using 0.24 mmol SnCl4¡¤5H2O and 4 mL water. Under more dilute conditions, 10.0 wt% 5-HMF was obtained using 0.12 mmol SnCl4¡¤5H2O and 15 mL water. We propose that under more concentrated reaction conditions the 5-HMF formed reacts further to produce LA. When chitin is treated similarly, no 5-HMF is produced but up to 12.7 wt% LA can be obtained. For comparison, 32.0 wt% LA was produced from 100 mg glucosamine hydrochloride using 0.26 mmol SnCl4¡¤5H 2O and 20 mL water. This corresponds to a yield of 59.4%. The SnCl4 forms SnO2 and HCl in solution and under similar conditions using SnO2 and HCl, chitosan formed 27.4 wt% LA.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

More research is needed about 2,2-Dimethylsuccinicanhydride

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Electric Literature of 17347-61-4, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.17347-61-4, Name is 2,2-Dimethylsuccinicanhydride, molecular formula is C6H8O3. In a Article£¬once mentioned of 17347-61-4

Catalytically Relevant Intermediates in the Ni-Catalyzed C(sp2)-H and C(sp3)-H Functionalization of Aminoquinoline Substrates

This Article describes the synthesis and characterization of cyclometalated aminoquinoline NiII sigma-aryl and sigma-alkyl complexes that have been proposed as key intermediates in Ni-catalyzed C-H functionalization reactions. These NiII complexes serve as competent catalysts for the C-H functionalization of aminoquinoline derivatives with I2. They also react stoichiometrically with I2 to form either aryl iodides or beta-lactams within minutes at room temperature. Furthermore, they react with AgI salts at -30 C to afford isolable five-coordinate NiIII species. The NiIII sigma-aryl complexes proved inert toward C(sp2)-I bond-forming reductive elimination under all conditions examined (up to 140 C in DMF). In contrast, a NiIII sigma-alkyl analogue underwent C(sp3)-N bond-forming reductive elimination at 140 C in DMF to afford a beta-lactam product. However, despite the ability of this latter NiIII species to participate in stoichiometric product formation, the complex was not a competent catalyst for beta-lactam formation. Overall, these results suggest against the intermediacy of NiIII species in these C-H functionalization reactions.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Awesome and Easy Science Experiments about Furan-2,4(3H,5H)-dione

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Application of 4971-56-6, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 4971-56-6, Furan-2,4(3H,5H)-dione, introducing its new discovery.

Synthesis of the hypoxic signaling inhibitor furospongolide

The first synthesis of the marine HIF-1 inhibitor furospongolide has been achieved in eight linear steps from geranyl acetate. Key steps include Schlosser sp3-sp3 cross-coupling and Sonogashira alkynylation of -bromobutenolide. Georg Thieme Verlag Stuttgart ¡¤ New York.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Discovery of Gamma-heptalactone

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Safety of Gamma-heptalactone, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 105-21-5, Name is Gamma-heptalactone, molecular formula is C7H12O2

Structural and Biochemical Characterization of AaL, a Quorum Quenching Lactonase with Unusual Kinetic Properties

Quorum quenching lactonases are enzymes that are capable of disrupting bacterial signaling based on acyl homoserine lactones (AHL) via their enzymatic degradation. In particular, lactonases have therefore been demonstrated to inhibit bacterial behaviors that depend on these chemicals, such as the formation of biofilms or the expression of virulence factors. Here we characterized biochemically and structurally a novel representative from the metallo-beta-lactamase superfamily, named AaL that was isolated from the thermoacidophilic bacterium Alicyclobacillus acidoterrestris. AaL is a potent quorum quenching enzyme as demonstrated by its ability to inhibit the biofilm formation of Acinetobacter baumannii. Kinetic studies demonstrate that AaL is both a proficient and a broad spectrum enzyme, being capable of hydrolyzing a wide range of lactones with high rates (kcat/KM > 105 M?1.s?1). Additionally, AaL exhibits unusually low KM values, ranging from 10 to 80 muM. Analysis of AaL structures bound to phosphate, glycerol, and C6-AHL reveals a unique hydrophobic patch (W26, F87 and I237), involved in substrate binding, possibly accounting for the enzyme?s high specificity. Identifying the specificity determinants will aid the development of highly specific quorum quenching enzymes as potential therapeutics.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Final Thoughts on Chemistry for Furan-2,4(3H,5H)-dione

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Recent developments on ultrasound-assisted one-pot multicomponent synthesis of biologically relevant heterocycles

Heterocycles are the backbone of organic compounds. Specially, N- & O-containing heterocycles represent privileged structural subunits well distributed in naturally occurring compounds with immense biological activities. Multicomponent reactions (MCRs) are becoming valuable tool for synthesizing structurally diverse molecular entities. On the other hand, the last decade has seen a tremendous outburst in modifying chemical processes to make them sustainable for the betterment of our environment. The application of ultrasound in organic synthesis is fulfilling some of the goals of ?green and sustainable chemistry? as it has some advantages over the traditional thermal methods in terms of reaction rates, yields, purity of the products, product selectivity, etc. Therefore the synthesis of biologically relevant heterocycles using one-pot multi-component technique coupled with the application of ultrasound is one of the thrusting areas in the 21st Century among the organic chemists. The present review deals with the ?up to date? developments on ultrasound assisted one-pot multi-component synthesis of biologically relevant heterocycles reported so far.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

New explortion of (S)-( )-5-Oxo-2-tetrahydrofurancarboxylic Acid

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Reference of 21461-84-7, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.21461-84-7, Name is (S)-( )-5-Oxo-2-tetrahydrofurancarboxylic Acid, molecular formula is C5H6O4. In a Article£¬once mentioned of 21461-84-7

Diastereocontrol in Glycosylation Reactions: Synthesis of beta-D and beta-L Dideocytidine Analogues

Expeditious and diastereoselective total syntheses of the antiviral agents, beta-L-ddC, beta-L-5FddC and beta-D-5FddC have been achieved in four steps from commercially available R-(-)-5-oxo-2-tetrahydrofurancarboxylic and its 2S isomer respectively.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Extended knowledge of Furan-2,4(3H,5H)-dione

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Bioactive compounds isolated from marine-derived microbes in China: 2009-2018

This review outlines the research that was carried out regarding the isolation of bioactive compounds from marine-derived bacteria and fungi by China-based research groups from 2009-2018, with 897 publications being surveyed. Endophytic organisms featured heavily, with endophytes from mangroves, marine invertebrates, and marine algae making up more than 60% of the microbial strains investigated. There was also a strong focus on fungi as a source of active compounds, with 80% of publications focusing on this area. The rapid increase in the number of publications in the field is perhaps most notable, which have increased more than sevenfold over the past decade, and suggests that China-based researchers will play a major role in marine microbial natural products drug discovery in years to come.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

A new application about (R)-(-)-5-Oxotetrahydrofuran-2-carboxylicacid

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Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Computed Properties of C5H6O4. Introducing a new discovery about 53558-93-3, Name is (R)-(-)-5-Oxotetrahydrofuran-2-carboxylicacid

1H and 13C NMR study of 2-hydroxyglutaric acid and its lactone

Determination of the level and absolute configuration of 2-hydroxyglutaric acid in a patient’s urine is a method of diagnosing two metabolic diseases. Such a determination can be done with the aid of NMR spectroscopic methods. In this paper the careful interpretation of 1H and 13C NMR spectra of this metabolite and its lactone measured under conditions used in biomedical assays is reported. The 1H chemical shifts and spin-spin coupling constants were derived using the total lineshape analysis method. Copyright

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Archives for Chemistry Experiments of 22530-98-9

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22530-98-9, Name is 4-Benzyldihydrofuran-2(3H)-one, belongs to Tetrahydrofurans compound, is a common compound. HPLC of Formula: C11H12O2In an article, once mentioned the new application about 22530-98-9.

Radical cyclization on solid support: Synthesis of gamma-butyrolactones

Synthesis of gamma-butyrolactones using radical cyclization on solid-phase has been achieved. Polymer-supported beta-bromoethylacetals were treated with tributyltin hydride in the presence of a catalytic amount of alpha,alpha’- azobisisobutyronitrile to generate intermediate carbon radicals which cyclize onto the intramolecular carbon-carbon double bond. The cyclization products were released by Jones oxidation from resin to give gamma-butyrolactones in good yields.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem