Tetrahydrofurans| Page 135 of 701 | Heterocyclic Building Blocks-Tetrahydrofuran

Liu, Qiaoyun’s team published research in Green Chemistry in 2020 | 97-99-4

Green Chemistry published new progress about Biomass. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Category: tetrahydrofurans.

Liu, Qiaoyun; Qiao, Botao; Liu, Fei; Zhang, Leilei; Su, Yang; Wang, Aiqin; Zhang, Tao published the artcile< Catalytic production of 1,4-pentanediol from furfural in a fixed-bed system under mild conditions>, Category: tetrahydrofurans, the main research area is catalytic pentanediol furfural fixed bed system.

Furfural is one of the most important biomass-derived chems. Its large-scale availability calls for the exploration of new transformation methods for further valorization. Here we report on the direct, one-step conversion of furfural into 1,4-pentanediols (1,4-PeDs) using a combination of Amberlyst-15 and Ru-FeOx/AC catalysts. It is interesting to find that the introduction of a suitable amount of FeOx results in a great improvement in the dispersion of Ru and a decrease in the Lewis acidity. Both XPS and H2-TPR show that there is electron transfer from Ru to Fe, and the electronic interaction facilitates the reduction of both Ru and Fe species. When used in combination with Amberlyst-15, the Ru-6.3FeOx/AC catalyst afforded the best performance with a 1,4-PeD yield of 86%; by contrast, Ru/AC free of FeOx only gave levulinic acid as the major product, demonstrating the key role of the acid/metal balance in the one-pot conversion of furfural to 1,4-PeD. Moreover, such a dual catalyst exhibited excellent durability within 175 h time-onstream.

Green Chemistry published new progress about Biomass. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Category: tetrahydrofurans.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Kumar, Abhinav’s team published research in ACS Applied Energy Materials in 2020-10-26 | 97-99-4

ACS Applied Energy Materials published new progress about Activation energy. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Related Products of 97-99-4.

Kumar, Abhinav; Srivastava, Rajendra published the artcile< Pd-Decorated Magnetic Spinels for Selective Catalytic Reduction of Furfural: Interplay of a Framework-Substituted Transition Metal and Solvent in Selective Reduction>, Related Products of 97-99-4, the main research area is selective reduction furfural palladium magnetic spinel.

The reduction of functional platform chems., such as furfural, to industrially important chems. and fuel requires precise modulation of surface reactivity of the catalyst to obtain the desired reactivity and selectivity. In this study, the selective reduction of furfural (FAL) to furfuryl alc. (FOL) and tetrahydrofurfuryl alc. (THFA) is achieved by the transition metal interplay in the framework structure of magnetic spinels Fe3O4 and by modulating the reaction medium. Herein, FAL is selectively and quant. reduced to FOL in water at very mild reaction conditions over Pd-decorated CuFe2O4, whereas FAL is selectively converted to THFA in hexane at mild reaction conditions over Pd-decorated NiFe2O4, using H2 as an economical reducing agent. The Pd loading, reaction temperature, H2 pressure, and reaction time are minimized to obtain the best selectivity toward THFA. Different modes of FAL adsorption occur on CuFe2O4 and NiFe2O4 surfaces. Dissociative adsorption of H2 occurs on Pd sites to form Pd-H species, followed by transfer hydrogenation from Pd-H to FAL adsorbed on spinels, leading to the formation of FOL or THFA. Efficient magnetic recyclability and the hot filtration test show that the catalyst exhibits no significant loss in the activity even after five recycles. Catalysts exhibit very high activity, selectivity, and low activation energy, which are very attractive for academic and industrial points of view.

ACS Applied Energy Materials published new progress about Activation energy. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Related Products of 97-99-4.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Povedano, M’s team published research in Pain management in 2019-03-01 | 58-97-9

Pain management published new progress about 58-97-9. 58-97-9 belongs to class tetrahydrofurans, and the molecular formula is C9H13N2O9P, Synthetic Route of 58-97-9.

Povedano, M; Martínez, Y; Tejado, A; Arroyo, P; Tebe, C; Lorenzo, J L; Montero, J published the artcile< Observational pilot study of patients with carpal tunnel syndrome treated with Nucleo CMP Forte™.>, Synthetic Route of 58-97-9, the main research area is carpal tunnel syndrome; electromyography; nucleotides; pain.

AIM: Carpal tunnel syndrome (CTS) is a very common entrapment neuropathy characterized by pain and paresthesia in the territory of the median nerve. Although this syndrome has a considerable impact on the patient’s quality of life, its medical treatment is far from optimal. MATERIAL & METHODS: We performed an observational study to evaluate Nucleo CMP ForteTM in patients with electromyography-confirmed, mild-moderate CTS. Pain was assessed using a visual analog scale, electromyogram and the SF-36. RESULTS: Pain decreased significantly after 6 months. Quality of life improved significantly in the pain dimensions. No significant differences were observed in electromyographic findings. No adverse events were reported. CONCLUSIONS: Nucleotides could prove useful for the nonsurgical treatment of CTS. Further studies are necessary to confirm this.

Pain management published new progress about 58-97-9. 58-97-9 belongs to class tetrahydrofurans, and the molecular formula is C9H13N2O9P, Synthetic Route of 58-97-9.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Kato, Shunsuke’s team published research in Polymers (Basel, Switzerland) in 2019 | 4415-87-6

Polymers (Basel, Switzerland) published new progress about Electric breakdown. 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, Safety of Cyclobuta[1,2-c:3,4-c’]difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone.

Kato, Shunsuke; Yusof, Fitri Adila Amat; Harimoto, Toyohiro; Takada, Kenji; Kaneko, Tatsuo; Kawai, Mika; Mitsumata, Tetsu published the artcile< Electric volume resistivity for biopolyimide using 4,4'-diamino-α-truxillic acid and 1,2,3,4-cyclobutanetetracarboxylic dianhydride>, Safety of Cyclobuta[1,2-c:3,4-c’]difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone, the main research area is biopolyimide film volume resistivity elec insulation property; biopolyimide; biopolymer; electric resistivity; polyimide.

Biopolyimides poly(ATA-CBDA), made from of 4,4′-diamino-α-truxillic acid di-Me ester (ATA) and 1,2,3,4-cyclobutanetetracarboxylic dianhydride (CBDA), is synthesized and measured its elec. volume resistivity at various exptl. conditions. The effects of film size, thickness, drying time, and the elec. field strength on elec. resistivity are investigated and compared with polyimide (Kapton). The elec. resistivity for all polyimide and biopolyimide are distributed in the range of 1015-1016 Ωcm, which shows that biopolyimide has high elec. insulation as well as polyimide. The elec. resistivity strongly depends on film thickness, which suggests that elec. resistivity is a function of elec. field strength. The critical elec. field for polyimide and biopolyimide films are determined to be 5.8 x 107 V/m and 3.2 x 107 V/m, resp. Humidity was found to strongly affect the elec. resistivity; ~1016 Ωcm at 34% RH and ~1013 Ωcm at 60% RH for both polyimide and biopolyimide films.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Goryanova, Bogdana’s team published research in Journal of the American Chemical Society in 2019-08-28 | 58-97-9

Journal of the American Chemical Society published new progress about Enzyme functional sites, active. 58-97-9 belongs to class tetrahydrofurans, and the molecular formula is C9H13N2O9P, Product Details of C9H13N2O9P.

Goryanova, Bogdana; Amyes, Tina L.; Richard, John P. published the artcile< Role of the Carboxylate in Enzyme-Catalyzed Decarboxylation of Orotidine 5'-Monophosphate: Transition State Stabilization Dominates Over Ground State Destabilization>, Product Details of C9H13N2O9P, the main research area is decarboxylation orotidine monophosphate decarboxylase transition state stabilization.

Kinetic parameters kex (s-1) and kex/Kd (M-1s-1) are reported for exchange for deuterium in D2O of the C-6 hydrogen of 5-fluororotidine 5′-monophosphate (FUMP) catalyzed by the Q215A, Y217F, and Q215A/Y217F variants of yeast orotidine 5′-monophosphate decarboxylase (ScOMPDC) at pD 8.1, and by the Q215A variant at pD 7.1-9.3. The pD rate profiles for wildtype ScOMPDC and the Q215A variant are identical, except for a 2.5 log unit downward displacement in the profile for the Q215A variant. The Q215A, Y217F and Q215A/Y217F substitutions cause 1.3-2.0 kcal/mol larger increases in the activation barrier for wildtype ScOMPDC-catalyzed deuterium exchange compared with decarboxylation, because of the stronger apparent side chain interaction with the transition state for the deuterium exchange reaction. The stabilization of the transition state for the OMPDC-catalyzed deuterium exchange reaction of FUMP is ca. 19 kcal/mol smaller than the transition state for decarboxylation of OMP, and ca. 8 kcal/mol smaller than for OMPDC-catalyzed deprotonation of FUMP to form the vinyl carbanion intermediate common to OMPDC-catalyzed reactions OMP/FOMP and UMP/FUMP. We propose that ScOMPDC shows similar stabilizing interactions with the common portions of decarboxylation and deprotonation transition states that lead to formation of this vinyl carbanion intermediate, and that there is a large ca. (19-8) = 11 kcal/mol stabilization of the former transition state from interactions with the nascent CO2 of product. The effects of Q215A and Y217F substitutions on kcat/Km for decarboxylation of OMP are expressed mainly as an increase in Km for the reactions catalyzed by the variant enzymes, while the effects on kex/Kd for deuterium exchange are expressed mainly as an increase in kex. This shows that the Q215 and Y217 side chains stabilize the Michaelis complex to OMP for the decarboxylation reaction, compared with the complex to FUMP for the deuterium exchange reaction. These results provide strong support for the conclusion that interactions which stabilize the transition state for ScOMPDC-catalyzed decarboxylation at a nonpolar enzyme active site dominate over interactions that destabilize the ground-state Michaelis complex.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Kawamata, Yuki’s team published research in Industrial Crops and Products in 2021 | CAS: 19444-84-9

3-Hydroxydihydrofuran-2(3H)-one(cas: 19444-84-9) is a 5-membered cyclic ester. It was obtained via tin-conversion of biomass-derived 1,3-dihydroxyacetone (DHA) and formaldehyde. And it may be employed as starting reagent in the synthesis of series of seco-pseudonucleoside synthons via aminolysis.Application of 19444-84-9

Kawamata, Yuki; Yoshikawa, Takuya; Koyama, Yoshihito; Ishimaru, Hiroya; Ohtsuki, Satoru; Fumoto, Eri; Sato, Shinya; Nakasaka, Yuta; Masuda, Takao published an article on January 31 ,2021. The article was titled 《Uniqueness of biphasic organosolv treatment of soft- and hardwood using water/1-butanol co-solvent》, and you may find the article in Industrial Crops and Products.Application of 19444-84-9 The information in the text is summarized as follows:

Biphasic organosolv treatment for soft- and hardwood using water/1-butanol was unique based on the correlation between liquid-phase states and solubility of the co-solvents when compared with a monophasic water/ethanol system. First, Pro II process simulator showed that water/1-butanol exhibited a biphasic system in the range of 1.6-19.0 mol/mol at a treatment temperature of 473 K. In addition, solubility of the co-solvents was evaluated using the Hildebrand solubility parameter (δ), which indicated that the biphasic system could simultaneously provide 28.5 and 42.0 MPa1/2 for the 1-butanol and water phase, resp. Each δ value appeared appropriate for lignin and hemicellulose dissolution because they were similar to those reported for lignin and a typical sugar. While hemicellulose could be removed by increasing water content in an organosolv of Japanese cedar sawdust, high lignin removal was achieved only under biphasic conditions. Carbon yield of each fraction (solid, 1-butanol-, and water-soluble fraction) and Py-GC/MS anal. revealed that lignin and hemicellulose could be recovered in the 1-butanol and water fractions, resp. The organosolv using Japanese cedar and willow was compared to the results when using monophasic water/ethanol. The results indicated that the co-solvent could not efficiently remove hemicellulose and lignin simultaneously because the monophasic system did not produce the level of solubility needed under the same conditions. In contrast, the biphasic water/1-butanol system achieved greater removal of hemicellulose and lignin compared to water/ethanol. The biphasic system was also applicable to separation of an industrial agricultural waste; sugarcane bagasse. Finally, the 2D-NMR spectra of 1-butanol-soluble lignin showed a trace amount of β-O-4 linkages in the lignin, indicating β-O-4 was cleaved via hydrolysis in the water phase during biphasic treatment. After reading the article, we found that the author used 3-Hydroxydihydrofuran-2(3H)-one(cas: 19444-84-9Application of 19444-84-9)

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Li, Qingyin’s team published research in Science of the Total Environment in 2021 | CAS: 19444-84-9

Recommanded Product: 19444-84-9On October 15, 2021 ,《Co-hydrothermal carbonization of swine manure and cellulose: Influence of mutual interaction of intermediates on properties of the products》 was published in Science of the Total Environment. The article was written by Li, Qingyin; Lin, Haisheng; Zhang, Shu; Yuan, Xiangzhou; Gholizadeh, Mortaza; Wang, Yi; Xiang, Jun; Hu, Song; Hu, Xun. The article contains the following contents:

Co-hydrothermal carbonization (HTC) of livestock manure and biomass might improve the fuel properties of the hydrochar due to the high reactivity of the biomass-derived intermediates with the abundant oxygen-containing functionalities. However, the complicated compositions make it difficult to explicit the specific roles of the individual components of biomass played in the co-HTC process. In this study, cellulose was used for co-HTC with swine manure to investigate the influence on the properties of the hydrochar. The yield of hydrochar obtained from co-HTC reduced gradually with the cellulose proportion increased, and the solid yield was lower than the theor. value. This was because the cellulose-derived intermediates favored the stability of the fragments from hydrolysis of swine manure. The increased temperature resulted in the reduction of the hydrochar yield whereas the prolonged time enhanced the formation of solid product. The interaction of the co-HTC intermediates facilitated the formation of O-containing species, thus making the solid more oxygen- and hydrogen-rich with a higher volatility. In addition, the co-HTC affected the evolution of functionalities like -OH and C=O during the thermal treatment of the hydrochar and altered its morphol. by stuffing the pores from swine manure-derived solid with the microspheres from HTC of cellulose. The interaction of the varied intermediates also impacted the formation of amines, ketones, carboxylic acids, esters, aromatics and the polymeric products in distinct ways. The experimental process involved the reaction of 3-Hydroxydihydrofuran-2(3H)-one(cas: 19444-84-9Recommanded Product: 19444-84-9)

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Li, Qingyin’s team published research in Science of the Total Environment in 2021 | CAS: 19444-84-9

3-Hydroxydihydrofuran-2(3H)-one(cas: 19444-84-9) may be employed as starting reagent in the synthesis of series of seco-pseudonucleoside synthons via aminolysis. It may be employed as starting reagent in the synthesis of enantiomerically pure orthogonally protected δ-azaproline, via Mitsunobu reaction.Application of 19444-84-9

Application of 19444-84-9On September 10, 2021 ,《Co-hydrothermal carbonization of swine and chicken manure: Influence of cross-interaction on hydrochar and liquid characteristics》 was published in Science of the Total Environment. The article was written by Li, Qingyin; Zhang, Shu; Gholizadeh, Mortaza; Hu, Xun; Yuan, Xiangzhou; Sarkar, Binoy; Vithanage, Meththika; Masek, Ondrej; Ok, Yong Sik. The article contains the following contents:

Swine and chicken manures are abundant solid wastes that can be converted into carbonaceous materials through hydrothermal carbonization (HTC). Owing to their unique biochem. compositions, co-HTC of these two types of manures may have significant implications for the generated products. We investigated the co-HTC of swine manure and chicken manure to understand the influence of the interaction between contrasting manures on the properties of the derived products. The results indicated that co-HTC treatment enhanced the formation of solid product and improved the C and N contents, heating value, and energy yield of the resulting hydrochar. Regarding the ignition temperature and comprehensive combustion index, the combustion properties of the hydrochar were enhanced owing to the mutual effect of the HTC intermediates. Addnl., the interaction of the intermediates significantly impacted the transfer of nitrogenous species and generation of organic acids and organic polymers with fused-ring structures. Therefore, co-HTC processing of animal manures could potentially provide a sustainable pathway for the conversion of animal waste into solid products with improved characteristics compared to those produced by treating the two feedstocks sep. After reading the article, we found that the author used 3-Hydroxydihydrofuran-2(3H)-one(cas: 19444-84-9Application of 19444-84-9)

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Wang, Xing’s team published research in Analyst (Cambridge, United Kingdom) in 2020 | CAS: 696-59-3

2,5-Dimethoxytetrahydrofuran(cas: 696-59-3) is a member of ether. When aromatic ethers are exposed to halogen in the presence or absence of a catalyst, they undergo halogenation, such as bromination.HPLC of Formula: 696-59-3

HPLC of Formula: 696-59-3In 2020 ,《A pro-gastrin-releasing peptide imprinted photoelectrochemical sensor based on the in situ growth of gold nanoparticles on a MoS2 nanosheet surface》 appeared in Analyst (Cambridge, United Kingdom). The author of the article were Wang, Xing; Deng, Hongping; Wang, Chen; Wei, Qiuxi; Wang, Yanying; Xiong, Xiaoxing; Li, Chunya; Li, Wenwen. The article conveys some information:

Lamellar MoS2 nanosheets were successfully prepared by hydrothermal synthesis using 1-(3-mercaptopropyl)-3-methyl-imidazolium bromine (MIMBr) ionic liquid as a sulfur source and a morphol. control agent, and sodium molybdate as a molybdenum source. Gold nanoparticles were assembled on the surface of MoS2 nanosheets by the in situ reduction of chloroauric acid at low temperatures to successfully fabricate AuNP/2D-MoS2 nanocomposites, thus improving photoelectrochem. response. AuNP/2D-MoS2 nanocomposites were used as photoelec. active materials modified onto a glassy carbon electrode surface to construct a photoelectrochem. (PEC) sensor. Then, using 1-(N-pyrrolpropyl)-3-methyl-imidazolium bromine (PMIMBr) ionic liquid as a functional monomer and pro-gastrin-releasing peptide (Pro-GRP) as a template, a molecularly imprinted polymerized ionic liquid film was electrochem. deposited on an AuNP/2D-MoS2/GCE surface. Upon removing the templates, a molecularly imprinted photoelectrochem. sensor was constructed for the sensing of a tumor marker, pro-gastrin-releasing peptide. Exptl. conditions including ascorbic acid concentration, polymerization conditions, incubation time, and pH value of the incubation solution have been optimized. Under the optimized conditions, the molecularly imprinted photoelectrochem. sensor can specifically detect the target protein Pro-GRP in the range of 0.02 ng mL-1-5 ng mL-1 with a detection limit of 0.0032 ng mL-1 (S/N = 3). The practicability of this photoelectrochem. sensor was demonstrated by accurately determining Pro-GRP in human serum samples. In addition to this study using 2,5-Dimethoxytetrahydrofuran, there are many other studies that have used 2,5-Dimethoxytetrahydrofuran(cas: 696-59-3HPLC of Formula: 696-59-3) was used in this study.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Torres-Pacheco, Luis J.’s team published research in Electrochimica Acta in 2020 | CAS: 19444-84-9

Name: 3-Hydroxydihydrofuran-2(3H)-oneOn September 1, 2020 ,《Sorbitol electro-oxidation reaction on sub<10 nm PtAu bimetallic nanoparticles》 was published in Electrochimica Acta. The article was written by Torres-Pacheco, Luis J.; De Leon-Rodriguez, Antonio; Alvarez-Contreras, Lorena; Guerra-Balcazar, Minerva; Arjona, Noe. The article contains the following contents: Sorbitol is a highly available and functionalized polyalc., with vast industrial usages and with great potential for fuel cells application. However, few studies were done regarding its electrochem. oxidation Monometallic Au, Pt and PtAu with different compositions from Pt-rich (such as Pt85Au15) to Au-rich (Pt10Au90) nanomaterials were synthesized. Several parameters like sorbitol and KOH concentration, scan rate, charge-transfer resistance, and temperature were tested. According with the physicochem. characterization, average particle sizes from 5.6 to 6.5 nm were found for all electrocatalysts, while Pt at. percentages of 85, 60, 40, and 10% were obtained. XPS revealed shifts in Pt 4f and Au 4f core-levels related to electron d. changes by the interaction between these elements and as a result, the electrocatalytic properties for the sorbitol electrooxidation reaction (SOR) were modified. The PtAu nanomaterials presented an increase of the c.d. with the raise of the KOH and sorbitol concentrations, being Pt40Au60/C the most active electrocatalyst displaying 40 mA mg-1 at 0.1M sorbitol in 2 M KOH with an onset potential of -0.50 V vs. normal H electrode. This onset potential value was more neg. to that typically reported for other polyols like glycerol and ethylene glycol. The reaction pathway of Pt/C, Au/C and Pt40Au60/C was followed by chromatog. and spectroscopic techniques, finding that the complex surfaces of these electrocatalysts were capable to carry the SOR via several electrons (from 2 to 24 e-). In this manner, the high electrocatalytic activity of Pt40Au60/C was attributed to the electron d. changes that promote a higher electron transfer forming shorter-chain byproducts. In the part of experimental materials, we found many familiar compounds, such as 3-Hydroxydihydrofuran-2(3H)-one(cas: 19444-84-9Name: 3-Hydroxydihydrofuran-2(3H)-one)

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem