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Disclosed are novel retinoid-related orphan receptor gamma (RORgamma) modulators and their use in the treatment of diseases mediated by RORgamma.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

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The jet-cooled fluorescence excitation spectra of states of tetrahydrofuran-3-one and tetrahydrothiophen-3-one have been recorded and analyzed. The carbonyl inversion bands, which arise from double-minimum potential energy functions in the excited states, were fit with functions of the form V = ax4 -bx2 or V = cx2 + d exp(-fx2). The furanone was found to have an inversion barrier in the S1(n,pi*) state of 1152 cm-1 (13.8 kJ mol-1) while the thiophenone has a barrier of 659 cm-1 (7.9 kJ mol-1). The two molecules have their potential energy minima for the S1(n,pi*) state at carbonyl wagging angles of 26 and 20, respectively. The results here, together with previous data for several other cyclic ketones, demonstrate that the inversion barrier increases with the ring angle strain at the ketone carbon atom.

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Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

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Preparation of 2,2-disubstituted and 2-monosubstituted alkenylboronic acid esters from aliphatic and aromatic ketones and aldehydes by the boron-Wittig olefination with bis[(pinacolato)boryl]methane was examined and applied on the multigram scale. The influence of the substrate steric and electronic features on the overall efficiency and stereochemical outcome of the reaction was studied. Additionally, a series of diversely functionalized (hetera)cycloalkylidenemethyl and (hetera)cycloalkyl boronic acid-derived building blocks was synthesized.

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Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

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The present invention relates to compounds of formula (I): and pharmaceutically acceptable salts thereof, wherein R1,R2. R3, R4, R5, R6, A and B are as defined herein. The invention also relates to pharmaceutical compositions comprising these compounds, methods of using these compounds in the treatment of various diseases and disorders, processes for preparing these compounds and intermediates useful in these processes

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

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22929-52-8, Name is Dihydrofuran-3(2H)-one, belongs to tetrahydrofurans compound, is a common compound. Product Details of 22929-52-8In an article, once mentioned the new application about 22929-52-8.

N-Alkylation of indoles is one of the important pathways for the construction of various biologically active indole molecules. Using ketones as N-alkylation reagent for indoles has been a great challenge not only because of the competing alkylation reaction of C-3 position but also because of the poor nucleophilicity of the nitrogen atom of indole, in addition to the steric hindrance and lower electrophilicity of the ketones. A dearomatization-rearomatization strategy has been developed for reductive cross-coupling of indoles with ketones in water. Various functional groups and other heterocyclic compounds are tolerated.

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Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

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The jet-cooled fluorescence excitation spectra of the S1(n, pi*) states of tetrahydrofuran-3-one, CH2OCH2CH2C=O, and tetrahydrothiophen-3-one, CH2SCH2CH2C=O, have been recorded and analyzed. The carbonyl inversion bands, which arise from double-minimum potential energy functions in the excited states, were fit with functions of the form V=ax4-bx2 or V=cx2+d exp(-fx2). The furanone was found to have an inversion barrier in the S1(n, pi*) state of 1152 cm-1(13.8 kJ/mol) while the thiophenone has a barrier of 659 cm-1 (7.9 kJ/mol). The two molecules have their potential energy minima for the S1(n, pi*) state at carbonyl wagging angles of 26 and 20, respectively. The results here, together with previous data for several other cyclic ketones, demonstrate that the inversion barrier increases with the ring angle strain at the ketone carbon atom.

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Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

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The toxic hallucinogen 25B-NBOMe is very rapidly degraded by human liver microsomes and has low oral bioavailability. Herein we report on the synthesis, microsomal stability, and 5-HT2A/5-HT2C receptor profile of novel analogues of 25B-NBOMe modified at the primary site of metabolism. Although microsomal stability could be increased while maintaining potent 5-HT2 receptor agonist properties, all analogues had an intrinsic clearance above 1.3 L/kg/h predictive of high first-pass metabolism.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

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A novel recyclable prolinamide-derived ionic-liquid-supported organocatalyst of asymmetric cross-aldol reactions in aqueous medium has been developed. In its presence, aromatic aldehydes react with cyclic or linear ketones to afford chiral aldol adducts in moderate to high yields and with excellent dr (anti/syn up to 96:4) and ee (81-99%) values that do not tend to decline over ten recycles of the catalyst. Furthermore, it allows a highly enantioselective catalytic synthesis of linear bis-aldols in aqueous medium.

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Reference:
Tetrahydrofuran – Wikipedia,
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The present invention provides compounds, compositions thereof, and methods of using the same.

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The invention provides a substituted alkynylpyridine compound with a structure represented by a formula (I) as described in the specification and a pharmaceutically acceptable salt and a medicinal preparation thereof. The compound is used for adjusting activity of protein kinase and adjusting intercellular or intracellular signal response. The invention also relates to a pharmaceutical composition including the compound provided by the invention and a method of applying the pharmaceutical composition in treating mammals, especially in treating highly proliferative diseases of the mankind.

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Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem