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Effective treatment of residue of acrylic acid production using a fluid-bed/fixed-bed system with low energy consumption

In order to effectively deal with large amounts of complex organic pollutants in the harmful distillation residues with low energy consumption, a novel two-stage fluid-bed/fixed-bed system was designed to catalyze oxidation of acrylic acid production residue. The effects of fluid-bed temperature, gaseous hourly space velocity (GHSV), and oxygen excess rate on the purification of acrylic acid production residue in the two-stage fluid-bed/fixed-bed system were studied to prove the feasibility of the method. The chemical oxygen demand (COD) of the discharged liquid was <100?mg/L, and the volatile organic compounds (VOCs) of the discharged gas amounted to <10?mg/m3 with a fluid-bed temperature of 380C, emulsified residue's GHSV of 0.28?L/(kgcat¡¤hr), and O2 excessive rate of more than 4.32. The result of techno-economics indicates the feasibility of the long-term operation of process. Results further illustrate the advantages of the proposed two-stage fluid-bed/fixed-bed system, which can treat acrylic acid production residue with high efficiency (COD?Tetrahydrofuran – Wikipedia,
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Autoxidation of Nonane and Decane: A Product Study

The autoxidation of nonane and decane has been shown to occur in three stages.The initial stage leads to alkyl hydroperoxide formation and in the second stage the hydroperoxide decomposes to produce alcohols and ketones as major products.These studies support the proposal that hydroperoxide decomposition in the second stage occurs by a radical-induced decomposition.In the third stage the products are oxidised in competition with the alkane.Under the conditions of the autoxidation, the alkanes produce gamma-lactones as the major ester components and carboxylic acids are formed in the latter stages of the autoxidation.Decan-2-one is shown to be the precursor of heptan-1-ol and octanal

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Exploiting rhizosphere microbial cooperation for developing sustainable agriculture strategies

The rhizosphere hosts a considerable microbial community. Among that community, bacteria called plant growth-promoting rhizobacteria (PGPR) can promote plant growth and defense against diseases using diverse distinct plant-beneficial functions. Crop inoculation with PGPR could allow to reduce the use of pesticides and fertilizers in agrosystems. However, microbial crop protection and growth stimulation would be more efficient if cooperation between rhizosphere bacterial populations was taken into account when developing biocontrol agents and biostimulants. Rhizospheric bacteria live in multi-species biofilms formed all along the root surface or sometimes inside the plants (i.e., endophyte). PGPR cooperate with their host plants and also with other microbial populations inside biofilms. These interactions are mediated by a large diversity of microbial metabolites and physical signals that trigger cell?cell communication and appropriate responses. A better understanding of bacterial behavior and microbial cooperation in the rhizosphere could allow for a more successful use of bacteria in sustainable agriculture. This review presents an ecological view of microbial cooperation in agrosystems and lays the emphasis on the main microbial metabolites involved in microbial cooperation, plant health protection, and plant growth stimulation. Eco-friendly inoculant consortia that will foster microbe?microbe and microbe?plant cooperation can be developed to promote crop growth and restore biodiversity and functions lost in agrosystems.

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Chemical Variation and Potential of Kaempferia Oils as Larvicide Against Aedes aegypti

The essential oil constituents of the Kaempferia species, specifically K. angustiflora, K. marginata and the three varieties of K. galanga, i.e., K. galanga 1, K. galanga 2 and K. galanga 3 from Chiang Mai Province, Thailand, were studied using gas chromatography-mass spectrometry (GC-MS). Monoterpene hydrocarbons and cinnamate derivatives were identified as the phytochemical markers of these Kaempferia species. The chemical variation of these oils was investigated using Principle Component Analysis (PCA). Cinnamate derivatives were found to be the main components in the three varieties of K. galanga, whereas K. marginata and K. angustiflora consisted of monoterpene hydrocarbons. Comparing the chemical variation between Kaempferia species in this research and other areas in previous reports revealed similar constituents in different quantities. Additionally, the three varieties of K. galanga showed significant larvicidal activity, with LC50 values ranging from 49.03 to 53.48 mug/ml. Based on partial least squares (PLS) regression, delta-3-carene, E-ethyl cinnamate, ethyl-p-methoxycinnamate, gamma-cadinene and n-pentadecane are the dominant compounds and contributed positively to the larvicidal activity.

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Electric Literature of 105-21-5, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 105-21-5, molcular formula is C7H12O2, introducing its new discovery.

Relevance of two-dimensional gas chromatography and high resolution olfactometry for the parallel determination of heat-induced toxicants and odorants in cooked food

The assessment of the dual impact of heating treatments on food safety and aroma is a major issue for the food sector. The aim of the present study was to demonstrate the relevance of multidimensional GC techniques, olfactometry and mass spectrometry for the parallel determination of process-induced toxicants and odorants in food starting with cooked meat as a food model. PAHs were analyzed by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry after extraction by accelerated solvent extraction (ASE-GC¡ÁGC-TOF/MS). Odour-active compounds were determined by dynamic headspace-GC hyphenated with eightbooth olfactometry and mass spectrometry (DH-GC-MS/8O) and DH-heart-cutting multidimensional GC hyphenated with olfactometry and mass spectrometry (DH-GC-GC-MS/O). For PAH determination, the GC¡ÁGC conditions consisted of a combination of a primary non-polar BPX-5 column and a secondary polar BPX-50 column, and a modulation period of 5s. In terms of linearity (R2 ranging from 0.985 to 0.997), recovery rate (84-111%) and limit of detection (5-65ng/kg of cooked meat), the ASE-GC¡ÁGC-TOF/MS method was found consistent with the multiresidue determination of 16 PAHs including benzo[a]pyrene in cooked meat. For aroma compounds, DH-GC-MS/8O and DH-GC-MS/O revealed 53 major meat odour-active compounds. A customized heart-cutting GC-GC-MS/O enabled the coeluting odour zones with high odour-activity to be resolved and revealed 15 additional odour-active compounds. Finally, these developments of multidimensional approaches were used to investigate the balance between 16 PAHs and 68 odour-active compounds generated with different cooking techniques.

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Volatile organic compounds and palatability of concentrates fed to lambs and ewes

The aromatic characteristics of concentrate feeds can affect feed intake in ruminants. In a previous study, the palatability of 14 feeds, mostly concentrates, was tested in lambs and mature dry ewes. In this study, the volatile profile of those feeds was measured by electronic nose analysis and gas chromatography-olfactometry as well as by mass spectrometry and the identified compounds were associated with their palatability. Another concentrate feed (barley meal) was used in the training of the animals for the palatability tests and was also subjected to the same instrumental analysis. Feed palatability by the lambs ranged from 0. mg/kg BW to 1379. mg/kg BW in a preference gradient that did not show clear cuts among types of feeds. The ewes, instead, showed clear preferences, with higher (P< 0.05) level of intake during the 6. min palatability tests for beet pulps, wheat grains, pea grains, and corn grains compared to the other feeds. The electronic nose showed a good separation between the most palatable and the least palatable feeds both in lambs and in ewes. The rank of total volatile organic compounds (VOCs) found in the feeds was, in decreasing order: beet pulps (27 VOCs), oat grains (26 VOCs), dehydrated alfalfa (20 VOCs), soybean hulls (19 VOCs), soybean meal 44 (18 VOCs), sunflower meal (16 VOCs), barley meal (15 VOCs), corn gluten meal and soybean meal 49 (14 VOCs), wheat brans (13 VOCs), corn middlings (12 VOCs), canola meal (7 VOCs), wheat grains (6 VOCs), corn grains and pea grains (5 VOCs). The aroma profile of the beet pulps, which were the most eaten feed by ewes and had intermediate intake by lambs, was characterized by a pleasant aroma of green and fruity notes because they were the richest of aldehydes (11 VOCs) and poor of sulphur compounds (2 VOCs). Dehydrated alfalfa and sunflower meal, which were commonly refused by lambs and ewes, were both rich of sulphur compounds (5 VOCs), whose unpleasant notes probably affected their palatability. Soybean meal 44, which was refused by the ewes and the least eaten of soybean by-products by lambs, and sunflower meal were characterized by a rich aroma profile but by a negative note due to the presence of methanamine, which gave an off-flavour identified as rotten fish odour. Oat grains, although characterized by pleasant flavours due to their richness of aldehydes (10 VOCs) and terpenes (7 VOCs), were refused by lambs and ewes. This was probably due to the presence, among the terpenes, of a unique compound (alpha-pinene), with a resin-pine flavour which is known to negatively affect intake of alfalfa pellets in lambs. Corn gluten meal, which was refused by lambs and ewes, was characterized by the presence of four sulphur compounds, which gave unpleasant notes of garlic and cooked potato to the feed and probably negatively affected its palatability. These results suggested that the aroma of several feeds might have affected animal short-term intake responses. The gas chromatography/olfactometry analysis can be a useful tool to identify potential candidate molecules that might explain the feeding choices of animals in terms of sensorial perceptions. However, more research is needed to better understand the specific compounds involved and to separate the flavour effects from the many other factors affecting palatability. I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 105-21-5, help many people in the next few years.COA of Formula: C7H12O2

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Odour-active compound profiles in Cantal-type cheese: Effect of cow diet, milk pasteurization and cheese ripening

Cantal cheese was made with either raw or pasteurized milk from cows fed either pasture or a hay and concentrate diet, and was analyzed after 3- and 6-month aging. The cheese aroma was rather mild for pasteurized-milk cheese and rather strong for raw-milk cheese, and was little affected by the cows’ feeding patterns. Gas chromatography of the volatile compounds coupled with a new 8-way olfactometry device revealed 42 odorous peaks. The major odour-active compounds were butanoic acid, 2,3-butanedione, 3-methylthio-propanal, hexanal, acetic acid, isobutanoic acid, and 1-octen-3-ol. The intensity of butanoic acid was much stronger in raw-milk than pasteurized-milk cheese. The intensities of isobutanoic acid,?pentanal, E-2-hexenal, cyclohexanone, tetramethylpyrazine and gamma-heptalactone were lower in the 6-month-aged than the 3-month-aged cheeses, and only ethylbenzene intensity was higher. Isopentanoic acid odour was weaker when the milk had been obtained from cows fed a pasture diet.

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African elephants use plant odours to make foraging decisions across multiple spatial scales

Mammalian herbivores are known to be extremely selective when foraging, but little is known about the mechanisms governing the selection of patches and, at a finer scale, individual plants. Visual examination and direct sampling of the vegetation have previously been suggested, but olfactory cues have seldom been considered. We examined the use of olfactory cues by foraging African elephants, Loxodonta africana, and asked whether they use plant odours to select specific patches or plants when making feeding decisions. Scent-based choice experiments between various preferred and nonpreferred plants were conducted across two spatial scales (between plants and between patches). We used coupled gas chromatography?mass spectrometry (GC?MS) analysis of headspace extracts of volatile organic compounds emitted by the different plant species to explore similarities among the overall odour profiles of each species. We found that elephants selected their preferred plant species across both spatial scales, probably using differences in plant odour profiles. The ability to differentiate between plant odours allowed elephants to reduce their search time by targeting preferred plant species both within a feeding station and between patches. This suggests that olfactory cues probably play an important role in driving herbivore foraging decisions across multiple spatial scales.

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Characterization of odorants in waxes for hot melt adhesives using sensory and instrumental analyses

Waxes are important additives in hot melt adhesives for improving the properties of the final product such as the melting point or viscosity. Up to one third of the formulation of the final product consists of waxes. For this purpose usually polyethylene (PE) waxes or Fischer-Tropsch (FT) waxes are used. Waxes affect the overall smell of hot melt adhesives, and often in a negative way. In our study the overall odor of five different waxes made by different manufacturing methods was characterized in order to classify the samples according to their overall smell. First of all the samples were evaluated by a trained sensory panel at room temperature and after heating to 80 C using descriptive analyses. Then the volatiles responsible for the overall smell of the samples were directly extracted using thermal desorption in combination with cryo-focusing and analyzed by gas chromatography-mass spectrometry-olfactometry (GC-MS/O). Moreover, the volatiles in the waxes were recovered using solvent extraction and isolated by solvent assisted flavour evaporation (SAFE). The most dominant odorants were then characterized by GC-O and odor extract dilution analysis (OEDA). Using these approaches 39 odorants having different chemical structures were successfully identified for the first time in waxes used as additives in hot melt adhesives. These odorants included alcohols with tallowy, soapy odor qualities such as 2-methyl-2-decanol, 2-methyl-2-dodecanol, and 1-undecanol, as well as a range of lactones such as gamma-decalactone and gamma-undecalactone having soapy, peach-like odor descriptions. The attributes of the odorants detected using GC analyses correlated with the descriptive analyses of the human sensory panel. This study indicates that the odor impact of waxes to hot melt adhesives depends on the manufacturing method of each single wax and that there is no clear trend for the preferential usage of PE or FT waxes.

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Minimal structural requirements of alkyl gamma-lactones capable of antagonizing the cocaine-induced motility decrease in planarians

We recently reported that the natural cyclic lactone, parthenolide, and related analogs prevent the expression of behavioral effects induced by cocaine in planarians and that parthenolide’s gamma-lactone ring is required for this effect. In the present work, we tested a series of alkyl gamma-lactones with varying chain length (1-8 carbons) to determine their ability to antagonize the planarian motility decrease induced by 200 muM cocaine. Alkyl lactones with up to a 4-carbon alkyl chain did not affect planarian motility or antagonized the cocaine-induced motility decrease; only the compound gamma-nonalactone (a gamma-lactone with a 5-carbon chain) was able to prevent the cocaine-induced behavioral patterns, while alkyl lactones with longer carbon chains failed to prevent the cocaine-induced effects. Thus, we conclude that the optimal structural features of this family of compounds to antagonize cocaine’s effect in this experimental system is a gamma-lactone ring with at a 5-carbon long functional group.

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