Yamaguchi, Sho published the artcileCascade approach to the synthesis of useful compounds using various natural carbon resources, Synthetic Route of 19444-84-9, the publication is Yuki Gosei Kagaku Kyokaishi (2016), 74(10), 975-983, database is CAplus.
A review. Due to the depletion of fossil fuels, natural carbon resources (i.e. biomass-derived sugars) have attracted increasing attention in recent years as an alternative carbon source. Although significant advances have been reported in the development of catalysts for the conversion of carbohydrates into key chems., only a limited range of products can be obtained. We herein describe the highly-selective cascade syntheses of a range of useful compounds using biomass-derived sugars and their decomposed oxygenates. We especially focus on the upgrade of C1 and C3 oxygenates generated from glucose, formaldehyde, and 1,3-dihydroxyacetone, resp., to yield useful compounds via C-C bond formation. The catalytic conversion reactions include (1) synthesis of α-hydroxy-γ-butyrolactone from 1,3-dihydroxyacetone and formaldehyde using tin compounds as catalysts, (2) synthesis of α-hydroxy-γ-substituted butyrolactone by cyclocondensation of 1,3-dihydroxyacetone with aldehydes in the presence of SnCl4·5H2O, and (3) synthesis of α-hydroxy-γ-butyrolactone from formaldehyde by formose reaction. The establishment of this novel synthetic methodol. to generate valuable chem. products from saccharides and their decomposed oxygenated materials renders carbohydrates a potential alternative carbon resource to fossil fuels.
Yuki Gosei Kagaku Kyokaishi published new progress about 19444-84-9. 19444-84-9 belongs to tetrahydrofurans, auxiliary class Tetrahydrofuran,Ester,Alcohol, name is 3-Hydroxydihydrofuran-2(3H)-one, and the molecular formula is C9H22OSi, Synthetic Route of 19444-84-9.
Referemce:
https://en.wikipedia.org/wiki/Tetrahydrofuran,
Tetrahydrofuran | (CH2)3CH2O – PubChem